Kamlet–Taft Solvation Parameters of Solvate Ionic Liquids
نویسندگان
چکیده
منابع مشابه
Criteria for solvate ionic liquids.
Certain concentrated mixtures of salts and solvents are not simply "solutions" anymore, but they may be described as "ionic liquids". In this perspective paper, we describe possible criteria for the new family of ionic liquids: "solvate" ionic liquids. This subclass of ionic liquids was originally proposed by Angell et al. in their recent review; however, their criteria remain to be debated. Co...
متن کاملDNA molecular solvation in neat ionic liquids.
The structural and molecular mechanism of double-stranded DNA (dsDNA) and single-stranded DNA (ssDNA) solvation in ten room-temperature ionic liquids (RTILs) is disclosed herein. We show that the Drew Dickerson B DNA structure solvated in neat RTILs based on imidazolium, oxazolium, pyrrolidinium, pyrimidinium and quaternary ammonium cations, combined with hexafluorophosphate and tetrafluorobrom...
متن کاملIonic liquids: Solvation ability and polarity*
The role of ionic liquids (ILs) as solvents in chemistry is limited by the poor understanding of the solvation phenomenon in these media. The usual classification criteria used for molecular solvents through various experimental measurements fail to insert ILs into a univocal classification for ILs. Here, we first discuss the unsuitability of the usual interpretative scheme for molecular liquid...
متن کاملCorrection: Determination of Kamlet-Taft parameters for selected solvate ionic liquids.
Correction for 'Determination of Kamlet-Taft parameters for selected solvate ionic liquids' by Daniel J. Eyckens et al., Phys. Chem. Chem. Phys., 2016, 18, 13153-13157.
متن کاملModeling Nmr Parameters of Oximes in Water and Ionic Liquids – Implications of Solvation Shell Structure
Organophosphophorus compounds (OP) has been widely used as pesticides and as warfare nerve agents. They act by phosphorylating the hydroxyl group of the Ser 203 residue of the Acetylcholinesterase (AChE) active site, inhibiting its catalytic activity, causing the cholinergic Syndrome [1]. Currently, the OP poisoning treatment consists in the use of reactivators, for example oximes, a class of c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ChemPhysChem
سال: 2016
ISSN: 1439-4235,1439-7641
DOI: 10.1002/cphc.201600361